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ChemicalBook--->CAS DataBase List--->415918-91-1

415918-91-1

415918-91-1 Structure

415918-91-1 Structure
IdentificationBack Directory
[Name]

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
[CAS]

415918-91-1
[Synonyms]

(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine
(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′
]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine
R-(3,5-Dioxa-4-Phospha-Cyclohepta[2,1-A:3,4-A']Dinaphthalen-4-yl)Bis[(1R)-1-Phenylethyl]aMine
(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS)
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f] [1,3,2]dioxaphosphepin-4-amine,99%e.e.
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
[Molecular Formula]

C37H32Cl2NO2P
[MDL Number]

MFCD04117687
[MOL File]

415918-91-1.mol
[Molecular Weight]

624.54
Chemical PropertiesBack Directory
[Melting point ]

102-103 °C
[alpha ]

+427° (c 0.83, CHCl3)
[Boiling point ]

710.7±63.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

Powder
[pka]

-0.57±0.20(Predicted)
[color ]

white
[Sensitive ]

moisture sensitive
[CAS DataBase Reference]

415918-91-1
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

36/37/38-22
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[HS Code ]

2934.99.4400
Questions And AnswerBack Directory
[Reactions]

  • A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  • Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
  • allylic esters.
  • Asymmetric hydrogenation.
  • Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
  • Asymmetric hydrovinylation.
  • Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
  • Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
  • Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
  • Palladium-catalyzed enantioselective diamination of alkyl dienes.
Reactions of 415918-91-1
Hazard InformationBack Directory
[Uses]

(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.
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