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ChemicalBook--->CAS DataBase List--->37172-53-5

37172-53-5

37172-53-5 Structure

37172-53-5 Structure
IdentificationBack Directory
[Name]

Methyl 2-Hexyl-3-oxocyclopentanecarboxylate
[CAS]

37172-53-5
[Synonyms]

DIHYDROJASMONATE
Einecs 253-379-1
DIHYDROISOJASMONAT
EXOVERT HIGH IMPACT
RUBARBUS HIGH IMPACT
TROPALONE HIGH IMPACT
DIHYDRO ISOJASMONATE(TM)
Methyldihydroisojasmonate
dihydroisojasmonate methyl ester
Methyl (2-amyl-3-oxocyclopentyl)acetate
2-N-Hexy-3-methoxycarbonylcyclopentanone
Methyl 2-hexyl-3-oxocyclopentancarboxylat
methyl 2-hexyl-3-oxocyclopentanecarboxylate
methyl 2-hexyl-3-oxocyclopentane-1-carboxylate
2-hexyl-3-oxo-cyclopentanecarboxylicacimethylester
Cyclopentanecarboxylicacid,2-hexyl-3-oxo-,methylester
2-HEXYL-3-OXO-CYCLOPENTANECARBOXYLIC ACID, METHYL ESTER
[EINECS(EC#)]

253-379-1
[Molecular Formula]

C13H22O3
[MDL Number]

MFCD00458917
[MOL File]

37172-53-5.mol
[Molecular Weight]

226.31
Chemical PropertiesBack Directory
[Boiling point ]

308.6±35.0 °C(Predicted)
[density ]

0.999±0.06 g/cm3(Predicted)
[vapor pressure ]

0.042Pa at 20℃
[Odor]

at 100.00 %. green jasmin floral fresh oily herbal
[Odor Type]

floral
[Water Solubility ]

186mg/L at 20.1℃
[LogP]

3.2 at 22℃
[EPA Substance Registry System]

Cyclopentanecarboxylic acid, 2-hexyl-3-oxo-, methyl ester (37172-53-5)
Hazard InformationBack Directory
[Chemical Properties]

Methyl 2-Hexyl-3-oxocyclopentanecarboxylate is a colorless liquid with a longlasting, floral, jasmine-like odor that has only little of the fatty aspect characteristic of many jasmine fragrances. The product has not been found in nature.
The title compound can be prepared by condensing an alkyl ??-bromocaprylate with a trialkyl propane-1,1,3-tricarboxylate to give a substituted cyclopentanone. Hydrolysis, decarboxylation, and esterification of the resulting monocarboxylic acid with methanol yield the desired ester. Trialkyl propane-1,1,3- tricarboxylates can be prepared by Michael addition of dialkyl malonates to alkyl acrylates.
The compound is used in perfumery in floral compositions.
[Flammability and Explosibility]

Notclassified
[Trade name]

Dihydro isojasmonateTM (PFW).
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