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ChemicalBook--->CAS DataBase List--->36198-87-5

36198-87-5

36198-87-5 Structure

36198-87-5 Structure
IdentificationBack Directory
[Name]

DIMETHYL TRIMETHYLSILYL PHOSPHITE
[CAS]

36198-87-5
[Synonyms]

Trimethylsiloxydimethoxyphosphine
DIMETHYL TRIMETHYLSILYL PHOSPHITE
Dimethyl trimethylsilyl phosphite,96%
O,O'-DIMETHYL(TRIMETHYLSILYL)PHOSPHITE
Dimethoxy[(trimethylsilyl)oxy]phosphine
Dimethyl(trimethylsilyl)phosphite, tech-95
O,O'-DIMETHYL(TRIMETHYLSILYL)PHOSPHITE, tech-95
Phosphorous acid, dimethyl trimethylsilyl ester
[EINECS(EC#)]

252-908-3
[Molecular Formula]

C5H15O3PSi
[MDL Number]

MFCD00075439
[MOL File]

36198-87-5.mol
[Molecular Weight]

182.23
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Boiling point ]

36-37 °C11 mm Hg(lit.)
[density ]

0.954 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.410(lit.)
[Fp ]

102 °F
[storage temp. ]

2-8°C
[form ]

liquid
[Specific Gravity]

0.954
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[BRN ]

1849308
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

Dimethyl trimethylsilyl phosphite may be used in the preparation of:
  • protected phosphoamino acid, Fmoc-Abu(PO3Me2)-OH, used in Fmoc/solid-phase peptide synthesis
  • phosphoenolpyruvate (PEP) via trimethylsilylation, bromination and Perkow reaction
  • sialyl phosphonate
  • sulfonamide phosphonates
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

10-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 2920 8/PG 2
[WGK Germany ]

3
[F ]

10-13
[TSCA ]

No
[HazardClass ]

3.2
[PackingGroup ]

III
Spectrum DetailBack Directory
[Spectrum Detail]

DIMETHYL TRIMETHYLSILYL PHOSPHITE(36198-87-5)1HNMR
DIMETHYL TRIMETHYLSILYL PHOSPHITE(36198-87-5)IR
DIMETHYL TRIMETHYLSILYL PHOSPHITE(36198-87-5)Raman
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