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ChemicalBook--->CAS DataBase List--->36016-40-7

36016-40-7

36016-40-7 Structure

36016-40-7 Structure
IdentificationBack Directory
[Name]

O-Mesitylenesulfonylhydroxylamine
[CAS]

36016-40-7
[Synonyms]

O-Mesitylenesulfonyl
O-(MESITYLSULFONYL)HYDROXYLAMINE
O-Mesitylenesulfonylhydroxylamine
O-mesitylenesulphonylhydroxylamine
amino 2,4,6-trimethylbenzenesulfonate
amino 2,4,6-trimethylbenzene-1-sulfonate
MSH, O-(Mesitylenesulfonyl)hydroxylamine
N-hydroxy-2,4,6-trimethylbenzenesulfonamide
2-[(Aminooxy)sulfonyl]-1,3,5-trimethylbenzene
O-(2,4,6-Trimethylphenyl)sulfonylhydroxylamine
O-(2,4,6-Trimethylbenzenesulfonyl)hydroxylamine
O-Mesitylenesulfonylhydroxylamine 2-[(Aminooxy)sulfonyl]-1,3,5-trimethylbenzene
[Molecular Formula]

C9H13NO3S
[MDL Number]

MFCD08275028
[MOL File]

36016-40-7.mol
[Molecular Weight]

215.27
Chemical PropertiesBack Directory
[Melting point ]

93-94 °C
[Boiling point ]

350.6±52.0 °C(Predicted)
[density ]

1.240
[storage temp. ]

Hygroscopic, -20°C Freezer, Under inert atmosphere
[solubility ]

DMSO (Slightly)
[form ]

Oil
[pka]

-4.59±0.70(Predicted)
[color ]

Pale Yellow to Pale Beige
[Stability:]

Do not dry. Will explode. Explosive.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22
[HS Code ]

2930909899
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Hydrochloric acid-->Diethyl ether-->Sulfuric acid-->N,N-Dimethylformamide-->Potassium carbonate-->Triethylamine-->Sodium chloride-->Hexane-->Acetonitrile-->1,4-Dioxane-->Hydroxylamine hydrochloride-->Chlorosulfonic acid-->Mesitylene-->PERCHLORIC ACID-->Mesitylene-2-sulfonyl chloride-->Ethyl acetohydroxamate
[Preparation Products]

1-amino-5-bromouracil
Hazard InformationBack Directory
[Uses]

O-Mesitylenesulfonylhydroxylamine is an oxidizing and aminating reagent with great potential to oxidatively eliminate the cysteine thiol modification to dehydroalanine.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 38, p. 1239, 1973 DOI: 10.1021/jo00946a045
Synthesis, p. 788, 1975 DOI: 10.1055/s-1975-23927
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