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ChemicalBook--->CAS DataBase List--->35660-94-7

35660-94-7

35660-94-7 Structure

35660-94-7 Structure
IdentificationBack Directory
[Name]

TIGLOYL CHLORIDE
[CAS]

35660-94-7
[Synonyms]

Tiglyl chloride
TIGLOYL CHLORIDE
Tiglic acid chloride
(E)-2-methylcrotonoyl chloride
2-Methylcrotonic acid chloride
(E)-2-Methyl-2-butenoyl chloride
(2E)-2-Methylbut-2-enoyl chloride
(E)-2-METHYL-BUT-2-ENOYL CHLORIDE
(E)-2,3-Dimethylacryloyl chloride
TRANS-2-METHYL-2-BUTENOYL CHLORIDE
3-cis-Methyl-methacryloyl chloride
2-Butenoyl chloride, 2-Methyl-, (2E)-
(E)-2-Methyl-2-butenoic acid chloride
trans-2-Methyl-2-butenoyl chloride >=97.0%
(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chlo
(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride
[EINECS(EC#)]

252-659-0
[Molecular Formula]

C5H7ClO
[MDL Number]

MFCD00800725
[MOL File]

35660-94-7.mol
[Molecular Weight]

118.56
Chemical PropertiesBack Directory
[Boiling point ]

145 °C
[density ]

1,08 g/cm3
[refractive index ]

n20/D 1.471
[Fp ]

22 °C
[storage temp. ]

Refrigerator
[solubility ]

soluble in Chloroform, Methanol
[form ]

clear liquid
[color ]

Colorless to Almost colorless
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

10-23/24/25-34
[Safety Statements ]

16-26-36/37/39-45
[RIDADR ]

3265
[WGK Germany ]

3
[HazardClass ]

8/3
[PackingGroup ]

II
[HS Code ]

2916199590
Hazard InformationBack Directory
[Chemical Properties]

Clear Colourless Oil
[Uses]

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.
[Synthesis Reference(s)]

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5
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