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ChemicalBook--->CAS DataBase List--->329735-87-7

329735-87-7

329735-87-7 Structure

329735-87-7 Structure
IdentificationBack Directory
[Name]

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
[CAS]

329735-87-7
[Synonyms]

Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II)
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),min.98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 98%
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),RuCl2[(S)-binap][(R,R)-dpen]
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediaMine]rutheniuM(II),98% RuCl2[(S)-binap][(R,R)-dpen]
[Molecular Formula]

C58H48Cl2N2P2Ru
[MDL Number]

MFCD02684565
[MOL File]

329735-87-7.mol
[Molecular Weight]

1006.94
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

?20°C
[form ]

Powder
[color ]

white to pale yellow
[Sensitive ]

air sensitive, store cold
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

The NOYORI catalysts are a ruthenium-based system containing a phosphine and 1,2-diamine ligand. The catalysts are used in the highly-efficient, enantio and diastereoselective hydrogenation of simple ketones, usually under the mild conditions of room temperature and 1-10 atm of hydrogen pressure. Reactions of 329735-87-7
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