| Identification | Back Directory | [Name]
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE | [CAS]
3196-23-4 | [Synonyms]
LABOTEST-BB LT00160081
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
methyl 1-bromocyclohexane-1-carboxylate
Methyl 1-broMocyclohexanecarboxylate 97%
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE, 97 %
1-Bromocyclohexanecarboxylic acid methyl ester
Cyclohexanecarboxylic acid, 1-bromo-, methyl ester | [Molecular Formula]
C8H13BrO2 | [MDL Number]
MFCD00134214 | [MOL File]
3196-23-4.mol | [Molecular Weight]
221.09 |
| Chemical Properties | Back Directory | [Boiling point ]
115-116 °C/19 mmHg (lit.) | [density ]
1.39 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.493(lit.) | [Fp ]
222 °F | [storage temp. ]
2-8°C | [form ]
liquid |
| Hazard Information | Back Directory | [Uses]
Methyl 1-bromocyclohexanecarboxylate may be used in the improved method of preparation of methyl 3-oxo-1-cyclohexene-1-carboxylate. It may be used in the Reformatsky synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones. | [General Description]
Methyl 1-bromocyclohexanecarboxylate reacts with zinc and substituted chalcones to yield the corresponding spiro-3,4-dihydropyran-2-one derivatives, 3-aryl-5-aryl-2-oxaspiro[5.5]undec-3-en-1-ones. Reformatsky reaction of methyl 1-bromocyclohexanecarboxylate with 2-aryl-2-oxoacetaldehyde is reported. Methyl 1-bromocyclohexanecarboxylate reacts with zinc and amides or methylamides of 3-aryl-2-cyanopropenoic acids to yield 5-aryl-1,3-dioxo-2-azaspiro[5.5]undecane-4-carbonitriles or 5-aryl-2-methyl-1,3-dioxo-2-azaspiro[5.5]undecane-4-carbonitriles. |
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| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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