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ChemicalBook--->CAS DataBase List--->263369-88-6

263369-88-6

263369-88-6 Structure

263369-88-6 Structure
IdentificationBack Directory
[Name]

BIS(2-METHOXYPHENYL)CHLORPHOSPHINE
[CAS]

263369-88-6
[Synonyms]

BIS(2-METHOXYPHENYL)CHLORPHOSPHINE
Chlorobis(2-methoxyphenyl)phosphine
Chlorobis(o-methoxyphenyl)phosphine
Bis(2-methoxyphenyl)chlorophosphine,
chloro-bis(2-methoxyphenyl)phosphane
Chlorobis(2-methoxyphenyl)phosphine, 98+%
Phosphinous chloride, P,P-bis(2-methoxyphenyl)-
[EINECS(EC#)]

679-144-7
[Molecular Formula]

C14H14ClO2P
[MDL Number]

MFCD08064037
[MOL File]

263369-88-6.mol
[Molecular Weight]

280.69
Chemical PropertiesBack Directory
[Melting point ]

111-114°C
[Boiling point ]

408.4±30.0 °C(Predicted)
[Water Solubility ]

Reacts with water.
[Sensitive ]

Moisture Sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS05
[Signal word ]

Danger
[Hazard statements ]

H318-H314
[Precautionary statements ]

P280-P305+P351+P338-P310-P260h-P301+P330+P331-P303+P361+P353-P405-P501a
[Hazard Codes ]

C
[Risk Statements ]

14-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN3261
[WGK Germany ]

1
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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