| Identification | Back Directory | [Name]
(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | [CAS]
259259-80-8 | [Synonyms]
(S)-AMAC
(S,S)-AMAC
(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)- | [Molecular Formula]
C32H38CoN2O4 | [MDL Number]
MFCD06797062 | [MOL File]
259259-80-8.mol | [Molecular Weight]
573.59 |
| Chemical Properties | Back Directory | [Melting point ]
242-246°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
powder to crystal | [color ]
Orange to Brown | [optical activity]
[α]/D 309°, c = 0.1 in chloroform |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
- Enantioselective borohydride reduction
- Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
- Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones
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