| Identification | Back Directory | [Name]
POTASSIUM TRIETHYLBOROHYDRIDE | [CAS]
22560-21-0 | [Synonyms]
POTASSIUM TRIETHYLBOROHYDRIDE
potassium triethylhydroborate
Potassium hydrotriethylborate
Potassium triethylhydridoborate
Potassium triethylhydroborate(1-)
Potassium triethylhydridoborate(1-)
potassium triethylborohydride solution
potassiumtriethylborohydride,calselect?kt,
Potassium triethylborohydride,1M solution inTHF
PotassiuM triethylborohydride solution 1.0 M in THF
Potassiumtriethylborohydride,1.0MinTHF,inSure/Sealbottle
potassiumtriethylborohydride,calselect?kt,intetrahydrofuran
Potassium triethylborohydride, 1M solution in THF, AcroSeal
PotassiuM triethylborohydride, 1.0 M solution in THF, SpcSeal
Potassium triethylborohydride, in tetrahydrofuran, 1M solution
POTASSIUM TRIETHYLBOROHYDRIDE, 1 M SOLUTION IN TETRAHYDROFURAN
POTASSIUM TRIETHYLBOROHYDRIDE, 1.0M SOLU TION IN TETRAHYDROFURAN
POTASSIUM TRIETHYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE | [EINECS(EC#)]
245-077-3 | [Molecular Formula]
C6H16BK | [MDL Number]
MFCD00011702 | [MOL File]
22560-21-0.mol | [Molecular Weight]
138.1 |
| Chemical Properties | Back Directory | [Appearance]
CLEAR SOLUTION | [density ]
0.902 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
Flammables + water-Freezer (-20°C)e area | [solubility ]
sol THF, diethyl ether, benzene, toluene. | [form ]
Solution | [color ]
Clear | [Sensitive ]
air sensitive, moisture sensitive |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR SOLUTION | [Uses]
- Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity
- Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon
Reagent for:
- Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine
- Dehydrogenation reactions
- Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates
- Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons
- Substitution reactions
| [reaction suitability]
reagent type: reductant | [Synthesis]
Potassium Triethylborohydride is prepared by the reaction of Potassium Hydride with Triethylborane in THF, or benzene. From Potassium Triisopropoxyborohydride and triethylborane in THF and from sodium triethylborohydride and potassium amalgam in benzene. | [storage]
The solution in THF is moisture- and air-sensitive, corrosive, and flammable. Reacts violently with water. Handle and store under nitrogen or argon in a cool place. Stable over prolonged periods of time. Use in a fume hood. Avoid contact with eyes, skin, and clothing. |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Infinity SCI
|
| Tel: |
400-400-1062016 17800804092 |
| Website: |
http://www.infsci.com |
| Company Name: |
Alfa Chemistry
|
| Tel: |
1-516-6625404 |
| Website: |
https://www.alfa-chemistry.com |
|