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ChemicalBook--->CAS DataBase List--->2230140-59-5

2230140-59-5

2230140-59-5 Structure

2230140-59-5 Structure
IdentificationBack Directory
[Name]

(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
[CAS]

2230140-59-5
[Synonyms]

Ni(IMes)(Di-tert-butyl Fumarate)2
(1,3-Dimesitylimidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
(1,3-Dimesityl-2,3-dihydro-1H-imidazol-2-ylidene)nickel(0) Bis(di-tert-butyl Fumarate)
[1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]bis(di-tert-butyl Fumarate) Nickel(0)
[Molecular Formula]

C45H60N2NiO8
[MOL File]

2230140-59-5.mol
[Molecular Weight]

815.67
Chemical PropertiesBack Directory
[form ]

powder
Safety DataBack Directory
[Symbol(GHS) ]


GHS08
[Signal word ]

Danger
[Hazard statements ]

H350-H372-H317-H334
[Precautionary statements ]

P260-P264-P270-P314-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P261-P285-P304+P341-P342+P311-P501
Hazard InformationBack Directory
[Uses]

Ni(IMes)(di-t-butyl fumarate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.
[reaction suitability]

reagent type: catalyst
reaction type: Cross Couplings
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