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ChemicalBook--->CAS DataBase List--->21797-13-7

21797-13-7

21797-13-7 Structure

21797-13-7 Structure
IdentificationBack Directory
[Name]

TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
[CAS]

21797-13-7
[Synonyms]

NSC 307191
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99%
PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX
TETRAKIS(ACETONITRILE)PALLADIUM(II) BIS(TETRAFLUOROBORATE)
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD)
Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98%
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9%
[Molecular Formula]

C8H12B2F8N4Pd
[MDL Number]

MFCD00043297
[MOL File]

21797-13-7.mol
[Molecular Weight]

444.24
Chemical PropertiesBack Directory
[Appearance]

Yellow powder
[Melting point ]

230 °C (dec.)(lit.)
[storage temp. ]

2-8°C
[form ]

Powder
[color ]

Yellow
[Water Solubility ]

Soluble in water
[Sensitive ]

Air Sensitive
Hazard InformationBack Directory
[Chemical Properties]

Yellow powder
[Uses]

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:
  • Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
  • Synthesis of dendritic SCS-pincer palladium complexes
  • Palladium complexes of click ligands
  • Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
[Uses]

Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.
[General Description]

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20
[Safety Statements ]

22-36/37/39-38
[RIDADR ]

UN2811
[WGK Germany ]

3
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29310099
Spectrum DetailBack Directory
[Spectrum Detail]

TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE(21797-13-7)1HNMR
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE(21797-13-7)IR
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