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ChemicalBook--->CAS DataBase List--->213343-65-8

213343-65-8

213343-65-8 Structure

213343-65-8 Structure
IdentificationBack Directory
[Name]

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
[CAS]

213343-65-8
[Synonyms]

(S,S)-ME-BPE-RH
(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh
(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
[Molecular Formula]

C22H40BF4P2Rh-
[MDL Number]

MFCD04038742
[MOL File]

213343-65-8.mol
[Molecular Weight]

556.21
Chemical PropertiesBack Directory
[Melting point ]

152.2-156.3 °C
[form ]

Crystalline Powder
[color ]

Orange to red to brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

22-24/25-26
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 213343-65-8
Hazard InformationBack Directory
[Uses]

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation
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