Identification | Back Directory | [Name]
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) | [CAS]
205495-66-5 | [Synonyms]
(S,S)TROST LIGAND(NAPHTHYL) min.94%rostligand(naphthyl) (S,S)-DACH-naphthyl Trost Ligand (S,S)-DACH-naphthyl Trost Ligand 95% 1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl) (1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94% (1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane (1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand (1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand | [Molecular Formula]
C52H44N2O2P2 | [MDL Number]
MFCD02684552 | [MOL File]
205495-66-5.mol | [Molecular Weight]
790.87 |
Chemical Properties | Back Directory | [Appearance]
white to off-white powder | [Melting point ]
232-237 °C | [alpha ]
-65.2° (c 1, CH3OH) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [pka]
13.43±0.40(Predicted) | [color ]
off-white | [optical activity]
[α]20/D -66.0°, c = 1 in methanol |
Questions And Answer | Back Directory | [Reactions]
The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles.
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