Identification | Back Directory | [Name]
PHENYL VINYL SULFOXIDE | [CAS]
20451-53-0 | [Synonyms]
NISTC20451530 (Vinylsulfinyl)benzene PHENYL VINYL SULFOXIDE VINYL PHENYL SULFOXIDE phenyl vinyl sulphoxide Sulfoxide, phenyl vinyl (Ethenylsulfinyl)benzene Phenyl ethenyl sulfoxide Phenyl (ethenyl) sulfoxide Benzene, (ethenylsulfinyl)- | [EINECS(EC#)]
243-831-6 | [Molecular Formula]
C8H8OS | [MDL Number]
MFCD00002086 | [MOL File]
20451-53-0.mol | [Molecular Weight]
152.21 |
Chemical Properties | Back Directory | [Boiling point ]
93-95 °C0.2 mm Hg(lit.)
| [density ]
1.139 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.585(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C | [form ]
liquid
| [color ]
deeply yellow
| [BRN ]
2039218 |
Hazard Information | Back Directory | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 61, p. 2260, 1996 DOI: 10.1021/JO960178X | [General Description]
Phenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78°C in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions. |
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Company Name: |
Energy Chemical
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Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
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