Identification | Back Directory | [Name]
Tributyl(2-phenylethenyl)stannane | [CAS]
19752-27-3 | [Synonyms]
Styryltributylstannane Tributyl(styryl)stannane Tributyl(2-phenylethenyl)stannane (2-Phenylethenyl)tributylstannane 1-(Tributylstannyl)-2-phenylethene [2-(Tributylstannyl)ethenyl]benzene tributyl(3-phenyl-2-propen-1-yl)Stannane Stannane, tributyl(3-phenyl-2-propen-1-yl)- | [Molecular Formula]
C21H36Sn | [MOL File]
19752-27-3.mol | [Molecular Weight]
407.22 |
Hazard Information | Back Directory | [Uses]
Tributyl(2-phenylethenyl)stannane is a phenylallylating agent as an anion equivalent; 3-carbon component in a [3 + 2] cycloaddition reaction
with α,β-unsaturated acylirons. | [Preparation]
Preparative Methods of Tributyl(2-phenylethenyl)stannane: by the coupling reaction of trans-cinnamylmagnesium bromide with Tri-n-butylchlorostannane (10-20%) or trapping of the lithiated derivative of allylbenzene (s-BuLi in
cyclohexane/TMEDA/THF) with tributylchlorostannane at -78 °C (90%). |
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ARENA CHEMICAL
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