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ChemicalBook--->CAS DataBase List--->1908442-13-6

1908442-13-6

1908442-13-6 Structure

1908442-13-6 Structure
IdentificationBack Directory
[Name]

3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2-(2,4,6-triisopropylbenzyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
[CAS]

1908442-13-6
[Synonyms]

ZJ-0163
3-(tert-butyl)-4-(2,6-dimethoxyphenyl)-2-(2,4,6-triisopropylbenzyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
rel-(2R,3R)-3-(tert-Butyl)-4-(2,6-dimethoxyphenyl)-2-(2,4,6-triisopropylbenzyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
1,3-Benzoxaphosphole, 4-(2,6-dimethoxyphenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-2-[[2,4,6-tris(1-methylethyl)phenyl]methyl]-, (2R,3R)-rel-
[Molecular Formula]

C35H47O3P
[MOL File]

1908442-13-6.mol
[Molecular Weight]

546.72
Chemical PropertiesBack Directory
[Boiling point ]

581.7±50.0 °C(Predicted)
[storage temp. ]

2-8°C
[form ]

powder
Safety DataBack Directory
[Symbol(GHS) ]


GHS02,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H304-H315-H336-H361d-H373-H412
[Precautionary statements ]

P201-P210-P273-P301+P310+P331-P302+P352-P308+P313
Hazard InformationBack Directory
[Uses]

HandaPhos forms a 1:1 complex with Pd(OAc)2 thereby arriving at a pre-catalyst, used at the ppm level, that enables Suzuki-Miyaura cross-couplings to be run under micellar catalysis in water at room temperature. To be used in tandem with Designer Surfactant TPGS-750-M.
[General Description]

This product has been enhanced for catalytic efficiency.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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