Identification | Back Directory | [Name]
METHYL CYANOFORMATE | [CAS]
17640-15-2 | [Synonyms]
cyklona Cyklon A CH3OC(O)CN METHYL CYANOFORMATE Methylcyanomethanoate Cyanoformic acid methyl cyanoformatemethylester Methyl carbonocyanidate Methyl cyanoforMate 99% Methyl cyanoformate ,98% Cyanoformate methyl ester cyano-formicacimethylester Cyanoformicacid,methylester 2-Oxo-2-methoxyacetonitrile Carbonocyanidic acid methyl oxalicacidmethylester-nitrile methylesterkyselinykyanmravenci carbonocyanidicacid,methylester Methylester kyseliny kyanmravenci Carbonocyanidic acid, methyl ester | [EINECS(EC#)]
241-626-6 | [Molecular Formula]
C3H3NO2 | [MDL Number]
MFCD00013420 | [MOL File]
17640-15-2.mol | [Molecular Weight]
85.06 |
Chemical Properties | Back Directory | [Appearance]
Colorless liquid; ethereal odor. Decomposedby alkalies and water. Soluble in alcohol, benzene,ether. | [Melting point ]
185-186 °C | [Boiling point ]
100-101 °C(lit.)
| [density ]
1.072 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.374(lit.)
| [Fp ]
79 °F
| [BRN ]
1742994 | [Uses]
Organic synthesis. | [EPA Substance Registry System]
Carbonocyanidic acid, methyl ester (17640-15-2) |
Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid; ethereal odor. Decomposedby alkalies and water. Soluble in alcohol, benzene,ether. | [Description]
Methyl cyanoformate is the organic compound with the formula CH3OC(O)CN. It is used as a reagent in organic synthesis as a source of the methoxy carbonyl group , in which context it is also known as Mander's reagent. It was also the active ingredient in the pesticide product Zyklon A. | [Purification Methods]
Purify the ester by fractionation through a 45cm glass helices packed column or a 30cm spinning band column. [Sheppard J Org Chem 27 3756 1962.] It has been distilled through a short Vigreux column (p 11), and further purified by recrystallisation from Et2O at -40o as white crystals which melt at room temperature. NMR: 4.0 ( C3), and IR: 2250 (CN) and 1750 (CO) cm-1 . [Childes & Weber JOrg Chem 41 3486 1976, Beilstein 2 III 1587.] |
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Sigma-Aldrich
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