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ChemicalBook--->CAS DataBase List--->1702744-45-3

1702744-45-3

1702744-45-3 Structure

1702744-45-3 Structure
IdentificationBack Directory
[Name]

-
[CAS]

1702744-45-3
[Synonyms]

Nicl(O-Tolyl)(Tmeda)
chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II)
CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA)
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
[Molecular Formula]

C13H23ClN2Ni
[MDL Number]

MFCD29037017
[MOL File]

1702744-45-3.mol
[Molecular Weight]

301.482
Chemical PropertiesBack Directory
[form ]

Powder
[color ]

dark-orange
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H317-H334-H350
[Precautionary statements ]

P201-P261-P280-P308+P313
[Risk Statements ]

45-42/43
[Safety Statements ]

53-22-36/37/39-45
[TSCA ]

No
Questions And AnswerBack Directory
[Reaction]

  1. Air-Stable Nickel precatalyst for cross-coupling
  2. Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)
Reactions of 1702744-45-3
Hazard InformationBack Directory
[Uses]

Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.
[reaction suitability]

core: nickel
reaction type: Cross Couplings
reagent type: catalyst
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