| Identification | Back Directory | [Name]
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% | [CAS]
167709-31-1 | [Synonyms]
SL-A121-2
(S)-3,5-t-Bu-MeOBIPHEP
(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine]
(S)-(-)-2,2'-Bis[di-(3,5-di-t-butylphenyl)-phosphino]-
6,6'-dimethoxy-1,1'-biphenyl
(S)-(-)-2,2'-Bis[di-(3,5-di-tert-butylphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYLPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
(S)-3,5-t-Bu-MeOBIPHEP, SL-A121-2, (S)-2,2μ-Bis[bis(3,5-di-tert-butyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] >=97%, optical purity ee: >=99% | [Molecular Formula]
C70H96O2P2 | [MDL Number]
MFCD09753001 | [MOL File]
167709-31-1.mol | [Molecular Weight]
1031.47 |
| Hazard Information | Back Directory | [Chemical Properties]
White powder | [Uses]
(S)-3,5-t-Bu-MeOBIPHEP can be used as a ligand in the stereoselective preparation of allenoates via palladium-catalyzed asymmetric carbonylation of propargylic carbonates. It can also be used in the C-C coupling reactions. | [General Description]
sold in collaboration with Solvias AG |
| Questions And Answer | Back Directory | [Reactions]
- Pd-catalyzed enantioselective Heck reaction.
- Used in enantioselective lactam synthesis via Pd-catalyzed intramolecular allylic alkylation.
- Used in enantioselective Au-catalyzed polycyclization reactions.
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