| Identification | Back Directory | [Name]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE | [CAS]
16456-81-8 | [Synonyms]
IRON TPP
RARECHEM AS SA 0004
PROTOPORPHYRIN IX FE(III) CHLORIDE
TETRAPHENYLPORPHYRIN IRON III CHLORIDE
IRON (III) TETRAPHENYLPORPHINE CHLORIDE
IRON (III) MESO-TETRAPHENYLPORPHINE CHLORIDE
MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE
Iron(III) meso-Tetraphenylporhpine Chloride
chloro(5,10,15,20-tetraphenyl)porphyrinatoiron(III)
MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE COMPLEX
5,10,15,20-Tetraphenyl-21H,23H-porphine iron(Ⅲ) chloride
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN IRON(III) CHLORIDE
Fe(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin)
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE, SYNTHETIC
5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride >=94% (HPLC)
5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride,meso-Tetraphenylporphyrin iron(III) chloride
Iron,chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N) di-(Fe-21,N22,N23,N24]-(SP-5-12)- | [Molecular Formula]
C44H28ClFeN4 | [MDL Number]
MFCD00012152 | [MOL File]
16456-81-8.mol | [Molecular Weight]
704.02 |
| Chemical Properties | Back Directory | [Appearance]
dark red or purple powder | [Melting point ]
300 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
crystal | [color ]
purple | [Stability:]
Stable. Incompatible with strong oxidizing agents, strong acids. | [Water Solubility ]
Insoluble in water. | [λmax]
418 nm | [InChIKey]
ZDYSAMCSFRQDMN-XBZZRTMISA-M | [CAS DataBase Reference]
16456-81-8 |
| Hazard Information | Back Directory | [Chemical Properties]
dark red or purple powder | [Uses]
Iron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions. | [Purification Methods]
Purify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.] |
| Spectrum Detail | Back Directory | [Spectrum Detail]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE(16456-81-8)Raman
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE(16456-81-8)IR
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE(16456-81-8)FT-IR
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