| Identification | Back Directory | [Name]
PffBT4T-2OD | [CAS]
1644164-62-4 | [Synonyms]
PffBT4T-2OD
Poly[(5,6-difluoro-2,1,3-benzothiadiazole-4,7-diyl)[3,3'''-bis(2-octyldodecyl)[2,2':5',2'':5'',2'''-quaterthiophene]-5,5'''-diyl]] | [Molecular Formula]
(C62H88F2N2S5)n | [MOL File]
1644164-62-4.mol |
| Chemical Properties | Back Directory | [form ]
powder | [λmax]
400-750 nm | [solubility ]
Dichlorobenzene or Chlorobenzene+dichlorobenzene (1:1 v/v) at elevated temperature ca. 110?°C |
| Hazard Information | Back Directory | [Description]
PffBT4T-2OD (PCE11) is a low band-gap (1.65 eV) semiconducting polymer for organic photovoltaics (OPVs), which has reached power conversion efficiencies (PCEs) approaching 11% . These efficiencies are a result of the high crystallinity of the polymer, providing excellent hole transport mobilities on the order of 10-2 cm2V-1s-1, and the ability to use a thick active layer, resulting in improved light absorption. | [Uses]
Requires hot ink processing (i.e. coating with ink at temperature 100-110 °C to ensure good coatability). |
| Questions And Answer | Back Directory | [Classification]
Benzothiadiazole, Fluorinated benzothiadiazole, Heterocyclic five-membered ring, Organic semiconducting materials, Low band gap polymers, Organic Photovoltaics, Polymer Solar Cells.
| [Applications]
PffBT4T-2OD (PCE11) is a low band-gap (1.65 eV) semiconducting polymer for organic photovoltaics (OPVs), which has reached power conversion efficiencies (PCEs) approaching 11% [1]. These efficiencies are a result of the high crystallinity of the polymer, providing excellent hole transport mobilities on the order of 10-2 cm2V-1s-1, and the ability to use a thick active layer, resulting in improved light absorption.
The size and position of the alkyl chains of PffBT4T-2OD are critical to its temperature dependant aggregation properties, enabling control over the aggregation and crystallisation of the polymer to produce an efficient donor:acceptor film morphology.
Polymer PCE11 was targeted by reacting 4,7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5,6-difluorobenzo[c][1,2,5]-thiadiazole with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene engaging Stille Coupling reaction.
![PCE11 (PffBT4T-2OD) synthesis with 4,7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5,6-difluorobenzo[c][1,2,5]-thiadiazole with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene as starting materials engaging Stille Coupling reaction](/NewsImg/2018-01-16/20181161652569674.jpg "PCE11 (PffBT4T-2OD) synthesis with 4,7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5,6-difluorobenzo[c][1,2,5]-thiadiazole with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene as starting materials engaging Stille Coupling reaction")
PCE11 (PffBT4T-2OD) synthesis with 4,7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5,6-difluorobenzo[c][1,2,5]-thiadiazole with 2,5-bis(trimethylstannyl)thieno[3,2-b]thiophene as starting materials engaging Stille Coupling reaction. |
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