| Identification | Back Directory | [Name]
LITHIUM TETRACHLOROCUPRATE | [CAS]
15489-27-7 | [Synonyms]
0.1MinTHF
LITHIUM TETRACHLOROCUPRATE
Tetrachloro copper lithiuM
DILITHIUM TETRACHLOROCUPRATE
LITHIUM TETRACHLOROCUPRATE(II)
Dilithium copper tetrachloride
DI-LITHIUM TETRACHLOROCUPRATE(II)
Lithiumtetrachlorocuprate,0.1MinTHF
Dilithium tetrachlorocuprate(II) solution
Cuprate(2-), tetrachloro-, dilithium, (SP-4-1)-
Lithium tetrachlorocuprate solution, 0.1M in THF
Dilithium tetrachlorocuprate, 0.1 M solution in THF
Dilithium tetrachlorocuprate(II) solution 0.1 in THF
Dilithium tetrachlorocuprate(II) solution 0.1 M in THF
LithiuM tetrachlorocuprate, 0.1 M solution in THF, J&KSeal
LithiuM tetrachlorocuprate, 0.1 M solution in THF, SpcSeal
Dilithium tetrachlorocuprate, 0.1M solution in THF, AcroSeal
DILITHIUM TETRACHLOROCUPRATE, 0.1M SOLUT ION IN TETRAHYDROFURAN
Dilithium Tetrachlorocopper(II) (ca. 2.5% in Tetrahydrofuran, ca. 0.1mol/L) | [EINECS(EC#)]
203-726-8 | [Molecular Formula]
Cl4CuLi2 | [MDL Number]
MFCD00011081 | [MOL File]
15489-27-7.mol | [Molecular Weight]
219.24 |
| Chemical Properties | Back Directory | [Appearance]
clear orange to brown-red solution | [Boiling point ]
66°C | [density ]
0.91 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
Flammables area | [solubility ]
Difficult to mix. | [form ]
Liquid | [color ]
Dark orange | [Specific Gravity]
0.91 | [Sensitive ]
Moisture Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Hazard Information | Back Directory | [Chemical Properties]
clear orange to brown-red solution | [Uses]
Lithium tetrachlorocuprate acts as catalyst used to couple alkyl halides with alkyl Grignard reagents, Used to halogenate pyrimidine nucleosides. Organic soluble copper catalyst used in catalytic quantities to improve the efficiency of halide and allylic acetate displacements with Grignard reagent, it is used in stoichiometric amounts to open epoxides and aziridines. | [Preparation]
Lithium tetrachlorocuprate is prepared in THF solution by reaction of Lithium Chloride (0.2 mol) and Copper(II) Chloride (0.1 mol). | [reaction suitability]
reagent type: catalyst
core: copper |
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