Identification | Back Directory | [Name]
(R)-VAPOL | [CAS]
147702-15-6 | [Synonyms]
(R)-VAPOL (S)-VAPOL (S)-VAPOL 97% (S)-VAPOL,99%e.e. (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL) (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL) (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL (3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL | [EINECS(EC#)]
200-838-9 | [Molecular Formula]
C41H28Cl2O2 | [MDL Number]
MFCD08459339 | [MOL File]
147702-15-6.mol | [Molecular Weight]
623.57 |
Chemical Properties | Back Directory | [Melting point ]
185-191 °C | [alpha ]
+125.0° (c 1.0, THF) | [Boiling point ]
712.2±60.0 °C(Predicted) | [density ]
1.286±0.06 g/cm3(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
Powder | [pka]
8.37±0.30(Predicted) | [color ]
white to pale yellow | [optical activity]
[α]20/D 128°, c = 1 in chloroform | [InChIKey]
FXFOHEGGSYVOKR-UHFFFAOYSA-N | [CAS DataBase Reference]
147702-15-6 |
Questions And Answer | Back Directory | [Reactions]
- Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
- Chiral ligand used in catalytic asymmetric aziridination.
- Chiral ligand used in catalytic asymmetric imino aldol reaction.
- Chiral ligand used in catalytic asymmetric Petasis reaction.
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