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ChemicalBook--->CAS DataBase List--->147702-13-4

147702-13-4

147702-13-4 Structure

147702-13-4 Structure
IdentificationBack Directory
[Name]

(S)-VANOL
[CAS]

147702-13-4
[Synonyms]

(S)-VANOL
(R)-VANOL
(R)-VANOL 97%
(R)-VANOL,99%e.e.
(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL
(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)
(2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
(2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
(2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL
(2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL
(R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol
[Molecular Formula]

C32H22O2
[MDL Number]

MFCD08459338
[MOL File]

147702-13-4.mol
[Molecular Weight]

438.52
Chemical PropertiesBack Directory
[Melting point ]

200-204 °C
[alpha ]

+362° (c 1.0, THF)
[Boiling point ]

580.1±50.0 °C(Predicted)
[density ]

1.251±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[form ]

Powder
[pka]

7.71±0.50(Predicted)
[color ]

white to pale yellow
[optical activity]

[α]20/D +310°, c = 1 in chloroform
[CAS DataBase Reference]

147702-13-4
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H315-H318-H335-H413
[Precautionary statements ]

P273-P280-P302+P352-P305+P351+P338+P310
[Hazard Codes ]

Xi
[Risk Statements ]

37/38-41
[Safety Statements ]

26-39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes. 
Reactions of 147702-13-4
Hazard InformationBack Directory
[Uses]

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
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