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ChemicalBook--->CAS DataBase List--->146504-07-6

146504-07-6

146504-07-6 Structure

146504-07-6 Structure
IdentificationBack Directory
[Name]

(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
[CAS]

146504-07-6
[Synonyms]

DACH-BOC
N-Boc-1R,2R-Cyclohexanediamine
(1R,2R)-N-Boc-1,2-cyclohexanediamine
(1R,2R)-N1-Boc-1,2-cyclohexanediamine
(1R)-trans-N-Boc-1,2-diaminocyclohexane
(1R,2R)-2-Amino-1-(Boc-amino)cyclohexane
(1R,2R)-1-AMINO-2-(BOC-AMINO)-CYCLOHEXANE
(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
Trans (1R,2R)-1N-Boc-cyclohexane-1,2-diamine
N-tert-Butoxycarbonyl-R,R-1,2-diaminocyclohexane
tert-Butyl N-((1R,2R)-2-aminocyclohexyl)carbamate
(1R,2R)-Cyclohexane-1,2-diamine, N1-BOC protected
(1R,2R)-N-tert.-Butoxycarbonylcyclohexane-1,2-diamine
(1R,2R)-Cyclohexane-1,2-diamine, N1-BOC protected 95%
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine 146504-07-6
(1R,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine
(1R,2R)-(-)-N-(t-Butoxycarbonyl)-1,2-cyclohexanediamine
(1R,2R)-2-Amino-1-(tert-butoxycarbonylamino)cyclohexane
((1R,2R)-2-Aminocyclohexyl)-carbamic acid tert-butyl ester
Carbamic acid, N-[(1R,2R)-2-aminocyclohexyl]-, 1,1-dimethylethyl ester
Carbamic acid, (2-aminocyclohexyl)-, 1,1-dimethylethyl ester,(1R-trans)-
[Molecular Formula]

C11H22N2O2
[MDL Number]

MFCD08726023
[MOL File]

146504-07-6.mol
[Molecular Weight]

214.3
Chemical PropertiesBack Directory
[Melting point ]

114-115℃
[Boiling point ]

322.1±31.0 °C(Predicted)
[density ]

1.02±0.1 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[form ]

powder to crystal
[pka]

12.26±0.40(Predicted)
[color ]

White to Almost white
[optical activity]

[α]/D -26±2°, c = 1 in chloroform
[BRN ]

7023564
[InChIKey]

AKVIZYGPJIWKOS-RKDXNWHRSA-N
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3259 8/PG 3
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

[HS Code ]

29242990
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
  • An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
  • A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.

[Definition]

ChEBI: (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine is an amine.
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