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    ChemicalBook--->CAS DataBase List--->1445972-29-1

    1445972-29-1

    1445972-29-1 Structure

    1445972-29-1 Structure
    IdentificationBack Directory
    [Name]

    Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [AdBrettPhos Palladacycle Gen. 3]
    [CAS]

    1445972-29-1
    [Molecular Formula]

    C56H74NO5PPdS
    [MDL Number]

    MFCD28411661
    [MOL File]

    1445972-29-1.mol
    [Molecular Weight]

    1010.66
    Chemical PropertiesBack Directory
    [Melting point ]

    251-253 °C
    [form ]

    solid
    [color ]

    brown to green
    Safety DataBack Directory
    [Symbol(GHS) ]


    GHS07
    [Signal word ]

    Warning
    [Hazard statements ]

    H319-H315
    [Precautionary statements ]

    P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
    Questions And AnswerBack Directory
    [Reaction]

    Palladium catalyst used in the highly selective monoarylation of ammonia. Reactions of 1445972-29-1
    Hazard InformationBack Directory
    [Uses]

    Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.

    Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts
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