| Identification | Back Directory | [Name]
METHYL (PHENYLSULFINYL)ACETATE | [CAS]
14090-83-6 | [Synonyms]
Einecs 237-936-6
Modafinil InterMediate
METHYL (PHENYLSULFINYL)ACETATE
methyl (phenylsulphinyl)acetate
METHYL 2-(PHENYLSULFINYL)ACETATE
methyl2-(benzenesulfinyl)acetate
methyl 2-(phenylsulphinyl)acetate
Methyl 2-phenylsulfinylacetate 98%
Methoxycarbonylmethyl phenyl sulfoxide
(Phenylsulfinyl)acetic acid methyl ester
2-(Phenylsulfinyl)acetic acid methyl ester
METHYL (+/-)-(PHENYLSULFINYL)ACETATE, 98 %
Acetic acid, (phenylsulfinyl)-, methyl ester
Acetic acid, 2-(phenylsulfinyl)-, methyl ester | [EINECS(EC#)]
237-936-6 | [Molecular Formula]
C9H10O3S | [MDL Number]
MFCD00002087 | [MOL File]
14090-83-6.mol | [Molecular Weight]
198.24 |
| Chemical Properties | Back Directory | [Melting point ]
52-54 °C(lit.)
| [Boiling point ]
130-131 °C0.5 mm Hg(lit.)
| [density ]
1.3339 (rough estimate) | [refractive index ]
1.5250 (estimate) | [Fp ]
>230 °F
| [form ]
solid | [BRN ]
1953383 |
| Hazard Information | Back Directory | [Description]
Methyl 2-(Phenylsulfinyl)acetate is a synthetic equivalent of a vinyl organometallic species; undergoes addition/elimination to aldehydes to give
conjugated dienoates or 4-hydroxy (2E)-enoates.
| [Uses]
Undergoes condensation reactions with aldehydes to form vinylic sulfoxides.1 | [General Description]
Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides. |
|
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