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ChemicalBook--->CAS DataBase List--->1375477-29-4

1375477-29-4

1375477-29-4 Structure

1375477-29-4 Structure
IdentificationBack Directory
[Name]

cataCXium A-Pd-G2
[CAS]

1375477-29-4
[Synonyms]

cataCXium A-Pd-G2
cataCXium(R) A Pd G2
2nd Gen. precatalyst cataCXium
Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) / CataCXium A-Pd-G2
[2'-(Amino)[1,1'-biphenyl]-2-yl][butylbis(tricyclo[3.3.1.1(3,7)]dec-1-yl)phosphine]chloropalladium
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine]chloro-
[Molecular Formula]

C36H49ClNPPd
[MDL Number]

MFCD22200549
[MOL File]

1375477-29-4.mol
[Molecular Weight]

668.64
Chemical PropertiesBack Directory
[Melting point ]

220°C (decomposition)
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[form ]

solid
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

cataCXium? A Pd G2 is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols.
[Uses]

Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
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