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ChemicalBook--->CAS DataBase List--->13520-78-0

13520-78-0

13520-78-0 Structure

13520-78-0 Structure
IdentificationBack Directory
[Name]

TUNGSTEN(VI) OXYCHLORIDE
[CAS]

13520-78-0
[Synonyms]

sten(VI) oxychL
TUNGSTEN OXYCHLORIDE
TUNGSTEN OXIDE CHLORIDE
TUNGSTEN OXYCHLORIDE 99%
TUNGSTEN(VI) OXYCHLORIDE
Tungsten oxytetrachloride
TUNGSTEN(VI)OXYCHLORIDE,98%
tungsten(vi) chloride oxide
tungsten tetrachloride oxide
Tungsten(VI) oxychloride 98%
tungsten(VI) oxytetrachloride
Wolfram(VI) tetrachlorideoxide
Tungsten chloride oxide(WCl4O)
Tungsten chloride oxide(WCl4O) (9CI)
Tungsten(VI) chloride oxide, Tungsten(VI) oxide chloride
[EINECS(EC#)]

236-863-7
[Molecular Formula]

Cl4OW
[MDL Number]

MFCD00011465
[MOL File]

13520-78-0.mol
[Molecular Weight]

341.65
Chemical PropertiesBack Directory
[Melting point ]

211 °C(lit.)
[Boiling point ]

337°C
[density ]

11.920
[solubility ]

reacts with H2O; soluble in benzene, CS 2
[form ]

red hygroscopic crystals
[color ]

red hygroscopic crystals, crystalline
[Water Solubility ]

decomposed by H2O; soluble CS2, benzene [KIR83] [HAW93]
[Sensitive ]

air sensitive, moisture sensitive
Hazard InformationBack Directory
[Chemical Properties]

Dark-red, acicular crystals. Decomposed by water and moist air. Keep in sealed glass container. Bp 227.5C, mp 211C, d 11.92. Soluble in carbon disulfide.
[Uses]

Incandescent lamps.
[Hazard]

Irritant.
[Description]

Tungsten(VI) oxytetrachloride, WOCl4, is a diamagnetic solid used to prepare other tungsten complexes. The orange-colored compound is soluble in nonpolar solvents, while it reacts with alcohols and water and forms adducts with Lewis bases.
[Preparation]

It consists of weakly associated square pyramidal monomers. WOCl4 is formed from WO3 or WCl6.
WO3 + 2SOCl2→WOCl4+2SO2
WCl6 + (Me3Si )2O→WOCl4+ 2Me3SiCl
Safety DataBack Directory
[Hazard Codes ]

Xi,C
[Risk Statements ]

36/37/38-34
[Safety Statements ]

26-37/39-45-36/37/39
[RIDADR ]

3262
[WGK Germany ]

3
[F ]

1-10
[HazardClass ]

8
[PackingGroup ]

III
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