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ChemicalBook--->CAS DataBase List--->131379-16-3

131379-16-3

131379-16-3 Structure

131379-16-3 Structure
IdentificationBack Directory
[Name]

4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
[CAS]

131379-16-3
[Synonyms]

Ethyl 4-(iodozincio)benzoate
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE
4-(Iodozincio)benzoic acid ethyl ester
4-(ethoxycarbonyl)phenylzinc iodide solution
4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 in THF
4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5M in THF
4-(ETHOXYCARBONYL)PHENYLZINC IODIDE, 0.5 M SOLUTION IN TETRAHYDROFURAN
4-(Ethoxycarbonyl)phenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
[Molecular Formula]

C9H9IO2Zn
[MDL Number]

MFCD00671982
[MOL File]

131379-16-3.mol
[Molecular Weight]

341.46
Chemical PropertiesBack Directory
[density ]

1.018 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
[Water Solubility ]

Reacts with water.
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
[CAS DataBase Reference]

131379-16-3
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

14-19-22-36/38-40-36/37-11
[Safety Statements ]

16-26-33-36-36/37
[RIDADR ]

UN 2056 3/PG 2
[WGK Germany ]

1
[HazardClass ]

4.3
Hazard InformationBack Directory
[Uses]

4-(Ethoxycarbonyl)phenylzinc iodide can be used as:
  • A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
  • A starting material in the synthesis of indazole derived glucagon receptor antagonists.
  • A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.

[Uses]

4-(Ethoxycarbonyl)phenylzinc iodide is used as pharmaceutical intermediates.
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