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ChemicalBook--->CAS DataBase List--->1302-78-9

1302-78-9

1302-78-9 Structure

1302-78-9 Structure
IdentificationBack Directory
[Name]

Bentonite
[CAS]

1302-78-9
[Synonyms]

hi-jel
magbond
volclay
tixoton
CI 77004
otaylite
BENTONITE
wilkinite
wilkonite
Optigel WM
Paper clay
Denver clay
Nanomer? PGV
Mud bentonite
FULLERS EARTH
imvitei.g.b.a
bentonite2073
colloidalclay
ENVIROCAT EPAD
Bentonite dust
bentonitepowder
MONTMORILLONITE
BENTONITE MAGMA
CALCIUMBENTONITE
KWK KRYSTAL KLEAR
southernbentonite
BENTONITE,CALCIUM-
volcalybentonitebc
MONTMORILLONITECLAY
BENTONITE,POWDER,NF
Bentonite812,organic
panthercreekbentonite
albagelpremiumusp4444
NANOCLAY, NANOMER PGV&
BENTONITE (SODIUM FORM)
ACIDICACTIVATEDBENTONITE
ORGANICACTIVATEDBENTONITE
BENTONITE,POWDER,TECHNICAL
ALKALINEACTIVATEDBENTONITE
BENTONITE-SFRESEARCH GRADE
Montmorillonite, Tixogel VP
Montmorillonite, Optigel WM
Bentonite Clay, Fine Powder
bentonite,sodiummontmorillonite
Nanoclay, hydrophilic bentonite
SUPERFINE ACTIVE BENTONITE 30-80 NM
BentonitePowder(AluminiumSilicateHydrate)
Dioxosilane oxo(oxoalumanyloxy)alumane hydrate
BENTONITE SELECTED FOR COAGULATION FACTORS ADSORPTION
Montmorillinite clay, bentonite, Nanomer(R) clay, Nanomer(R) PGV
[EINECS(EC#)]

215-108-5
[Molecular Formula]

Al2O3.4(SiO2).H2O
[MDL Number]

MFCD00130611
[Molecular Weight]

360.31
Chemical PropertiesBack Directory
[Appearance]

Bentonite is a light yellow, creamy, pale brown or gray to black powder or granules.
[density ]

2~3g/cm3
[solubility ]

Practically insoluble in water and in aqueous solutions. It swells with a little water forming a malleable mass.
[form ]

powder
[color ]

Light yellow or green, cream,pink, gray to black solid
[Odor]

odorless, sl. earthy taste
[Stability:]

Stable.
[Water Solubility ]

Insoluble in water and forms a colloidal solution.
[Merck ]

14,1055
[Dielectric constant]

8.1(Ambient)
[Exposure limits]

ACGIH: TWA 1 mg/m3
[Uses]

bentonite (bentonite clay) is used to regulate the viscosity and suspension properties of a cosmetic formulation. It also acts as an overall formula stabilizer. Bentonite’s water-absorption capabilities allow it to form a gelatinous mass. Considered a noncomedogenic raw material, bentonite is a colloidal aluminum silicate clay.
[CAS DataBase Reference]

1302-78-9
[EPA Substance Registry System]

Bentonite (1302-78-9)
Hazard InformationBack Directory
[Chemical Properties]

gel, or solid if dry
[Usage]

filler in cosmetics and other products, gel, or solid if dry
[Potential Exposure]

This material is used as Fuller’s earth; as a mineral, natural, or synthetic fiber; as an emulsifier for oils; as a base for plasters; in cosmetics, in polishes and abrasives; as a food additive and others. Bentonites are aluminate silicate and can contain crystalline silica. The content varies widely from less than 1% to about 24% .
[First aid]

Inhalation: Move person to fresh air. Seek medical attention if necessary. Skin: Wash with water. Eyes: Wash with water as needed. Seek medical attention if necessary. Ingestion: Seek medical attention if necessary.
[Shipping]

Bentonite is not cited in the DOT Performance- Oriented Packaging Standards.
[Incompatibilities]

Substance is a weak acid in water; avoid contact with strong alkaline material. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
[Description]

Bentonite is a light yellow, creamy, palebrown or gray to black powder or granules. These chemicals contain 1- 24% crystalline silica (O2Si). Specificgravity (H2O:1)=2.5. Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability 1,Reactivity 0. Insoluble in water
[Waste Disposal]

Land fill disposal.
[Definition]

A type of clay that is used as an adsorbent in making paper. The gelatinous suspension it forms with water is used to bind together the sand for making iron castings. Chemically bentonite is an aluminosilicate of variable composition.
[Production Methods]

Bentonite is a native, colloidal, hydrated aluminum silicate, found in regions of Canada and the USA. The mined ore is processed to remove grit and nonswelling materials so that it is suitable for pharmaceutical applications.
[General Description]

Bentonite is comprised primarily of the smectite group (montmorillonite) of clay minerals. It is widely used in various industrial applications such as clarification of edible and mineral oils, paints, cosmetics, and pharmaceuticals. It is also used as an adsorbent for the elimination of pollutants from wastewater.
The swelling property of bentonite is used to produce viscous water suspensions for bonding, plasticizing, and suspending applications. The presence of a large surface area of bentonite is due to the colloidal dispersion of the particles is the main reason for its application as an insecticide carrier, an emulsifier, and an emulsion stabilizer.
[Agricultural Uses]

Bentonite, also known as montmorillonite, volcanic clay, soap clay and amargosite, is a soft, plastic, lightcolored, porous rock consisting largely of colloidal silica. Composed essentially of clay minerals, it swells extensively when wet. Bentonite belongs chiefly to the montmorillonite group and has two varieties: (a) sodium bentonite, with a high swelling capacity in water, and (b) calcium bentonite, with negligible swelling capacity.
Bentonite is used variously as a suspending aid, a gelatinous slurry to extinguish fire, a paint thickener, and as a sealant for earthen pots. Bentonite is also widely used in metallurgy, soap manufacture, and in petroleum refining because of its high decolorizing power and strong adsorbing capacity.
[Agricultural Uses]

Clays exist in many forms, of which montmorillonite is one form. Kaolinite and montmorillonite, which are clay minerals, have different layer structures with differing abilities to absorb and retain water, and to adsorb and exchange cations.
Montmorillonites have an expanding structure (2: 1) and have high cation exchange capacity (80 to 120 mg per 100 g). They have abundant black clay soils. Other minerals in this group are biedellite and nontronite.
[Pharmaceutical Applications]

Bentonite is a naturally occurring hydrated aluminum silicate used primarily in the formulation of suspensions, gels, and sols, for topical pharmaceutical applications. It is also used to suspend powders in aqueous preparations and to prepare cream bases containing oil-in-water emulsifying agents.
Bentonite may also be used in oral pharmaceutical preparations, cosmetics, and food products. In oral preparations, bentonite, and other similar silicate clays, can be used to adsorb cationic drugs and so retard their release. Adsorbents are also used to mask the taste of certain drugs.
Bentonite has been investigated as a diagnostic agent for magnetic resonance imaging.
Therapeutically, bentonite has been investigated as an adsorbent for lithium poisoning.
[Safety]

Bentonite is mainly used in topical pharmaceutical formulations but has also been used in oral pharmaceutical preparations, food products, and cosmetics.
Following oral administration, bentonite is not absorbed from the gastrointestinal tract. Bentonite is generally regarded as a nontoxic and nonirritant material.
LD50 (rat, IV): 0.035 g/kg
[storage]

Bentonite is hygroscopic, and sorption of atmospheric water should be avoided.
Aqueous bentonite suspensions may be sterilized by autoclaving. The solid material may be sterilized by maintaining it at 1708℃ for 1 hour after drying at 1008℃.
Bentonite should be stored in an airtight container in a cool, dry place.
[Regulatory Status]

Accepted in Europe as a food additive in certain applications. Included in the FDA Inactive Ingredients Database (oral capsules, tablets and suspensions, topical suspensions, controlled release transdermal films and vaginal suppositories). Included in nonparenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.
Safety DataBack Directory
[Risk Statements ]

20/22-8
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[RTECS ]

CT9450000
[TSCA ]

Yes
[Safety Profile]

Poison by intravenous route causing blood clotting. Questionable carcinogen with experimental tumorigenic data.
[Hazardous Substances Data]

1302-78-9(Hazardous Substances Data)
[Toxicity]

LD50 intravenous in rat: 35mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium carbonate-->Mineral oil
[Preparation Products]

Montmorillonite K10-->anti water resistance to alkali,anti low temperature coating-->SODIUM ALUMINUM OXIDE-->medium temperature Shift catalysts-->medium(high)temperature Shift catalysts-->Oxytocin-->K-CATALYST-->Bentonite,calcium base-->ALUMINUM SILICATE-->clay activated for developer
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bentonite(1302-78-9).msds
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