Identification | Back Directory | [Name]
(1,10-Phenanthroline)(trifluoroMethyl)copper(I), 95% | [CAS]
1300746-79-5 | [Synonyms]
Trifluoromethylator (1,10-Phenanthroline)(trifluoromethyl)copper (1,10-Phenanthroline)(trifluoroMethyl)copper(I), 95% TrifluoroMethyl(1,10-phenanthroline)copper(I), 95% TrifluoroMethylator Trifluoromethyl(1,10-phenanthroline)copper(I), 95% Trifluoromethylator(R) | [Molecular Formula]
C13H8CuF3N2 | [MDL Number]
MFCD19690901 | [MOL File]
1300746-79-5.mol | [Molecular Weight]
312.757 |
Chemical Properties | Back Directory | [Melting point ]
>230°C (dec.) | [storage temp. ]
2-8°C | [form ]
Solid | [color ]
Orange | [Sensitive ]
air sensitive, moisture sensitive, store cold | [InChIKey]
CUQZQRIIFNWQSJ-UHFFFAOYSA-N | [CAS DataBase Reference]
1300746-79-5 |
Questions And Answer | Back Directory | [Reaction]
Reagent used for the perfluoromethylation of arenes and aryl bromides and iodides.
Catalyst used in the copper-mediated perfluoroalkylation of heteroaryl bromides.
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Hazard Information | Back Directory | [Uses]
(1,10-Phenanthroline)(trifluoromethyl)copper is used as a catalyst in the oxtidative trifluoromethylation of heteroarenes. | [Uses]
New versatile reagent for the trifluoromethylation of various aryls/heteroaryls. | [General Description]
(1,10-Phenanthroline)(trifluoromethyl)copper(I) [(Phen)Cu-CF3] can be prepared by treating [CuOt-Bu]4 with 1,10-phenanthroline, followed by the addition of (trifluoromethyl)trimethylsilane (CF3TMS). It is an easily handled, thermally stable, single-component reagent. |
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