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ChemicalBook--->CAS DataBase List--->12672-29-6

12672-29-6

12672-29-6 Structure

12672-29-6 Structure
IdentificationBack Directory
[Name]

AROCLOR 1248, 1X1ML, ISO, 1UG/ML
[CAS]

12672-29-6
[Synonyms]

kanechlor400
PCB Aroclor 1248
chlorodiphenyl(48%cl)
aroclor 1248 solution
Aroclor 1248 (PCB 1248)
AROCLOR 1248, 50MG, NEAT
[40cfr136(1986)]pcb-1248
Aroclor 1248 (High Level)
Aroclor 1248 @35 μg/mL in MeOH
Aroclor 1248 @100 μg/mL in MeOH
Aroclor 1248 @1000 μg/mL in MeOH
AROCLOR 1248, 1X1ML, ISO, 1UG/ML
Polychlorinated biphenyl (48% Cl)
Aroclor 1248@1000 μg/mL in Hexane
Aroclor 1248@35 μg/mL in Isooctane
aroclor1248referencestandardforclp
AROCLOR 1248, 1X1ML, ISO, 1000UG/ML
AROCLOR 1248, 1X1ML, MEOH, 200UG/ML
polychlorinatedbiphenyl(aroclor1248)
AROCLOR 1248, 1X1ML, MEOH, 1000UG/ML
AROCLOR 1248, 1X1ML, HEXANE 1000UG/ML
Aroclor 1248@500 ppm in Transformer Oil
PCB Aroclor 1248 @5.0 mg/mL in Isooctane
Aroclor 1248@50 ppm w/w in Transformer oil
AROCLOR 1248, 1X5ML, TRANSFORMER OIL 500 MG/KG
aroclor 1248, 48 perc.cl, pcb c12h7cl3 and c12h6cl4 and c12h5cl5
Polychlorinated biphenyl (Aroclor 1248): (Chlorodiphenyl (48% Cl))
[EINECS(EC#)]

208-759-1
[Molecular Formula]

N/A
[MDL Number]

MFCD01779891
Chemical PropertiesBack Directory
[Melting point ]

63.91°C (estimate)
[Boiling point ]

370.42°C (rough estimate)
[density ]

1.4100 (estimate)
[vapor pressure ]

1.835 at 25 °C (estimated using GC retention data, Foreman and Bidleman, 1985)
[refractive index ]

1.6130 (estimate)
[Fp ]

11 °C
[storage temp. ]

room temp
[solubility ]

Benzoic acid (10.0 wt % at 32 °C) and paraffin (2.0 wt % at 28 °C) (Monsanto, 1960).
[Water Solubility ]

0.1mg/L(20 ºC)
[Henry's Law Constant]

3.67 at 25 °C (Slinn et al., 1978)
[Exposure limits]

Potential occupational carcinogen. NIOSH REL: TWA 1.0 g/m3, IDLH 5 mg/m3.
[EPA Substance Registry System]

Aroclor 1248 (12672-29-6)
Safety DataBack Directory
[Hazard Codes ]

Xi,N,T,F,Xn
[Risk Statements ]

36/37/38-50/53-33-39/23/24/25-23/24/25-11-67-65-38-62-51/53-48/20-52/53-45
[Safety Statements ]

26-61-60-35-45-36/37-16-7-62-33-29-9-36-53
[RIDADR ]

2315
[WGK Germany ]

3
[RTECS ]

TQ1358000
[HazardClass ]

9
[PackingGroup ]

II
[Safety Profile]

Suspected human carcinogen. Moderately toxic by skin contact. Experimental teratogenic and reproductive effects. When heated to decomposition it emits toxic fumes of Cl-. Used in heat transfer, hydraulic fluids, lubricants, and insecticides. See also POLYCHLORINATED BIPHENYLS.
[Hazardous Substances Data]

12672-29-6(Hazardous Substances Data)
[Toxicity]

Acute oral LD50 for rats 11 g/kg (quoted, RTECS, 1985).
Hazard InformationBack Directory
[General Description]

Viscous oily liquid.
[Air & Water Reactions]

Insoluble in water.
[Reactivity Profile]

Simple aromatic halogenated organic compounds are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: Toxic irritant. Hazardous decomposition products.
[Fire Hazard]

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
[Chemical Properties]

Viscous, oily, light yellow to yellow-green, mobile, dense, nonflammable liquid with a faint odor
[Uses]

In epoxy resins to improve adhesion and resistance to chemical attack; as an insulator fluid for electric condensers and as an additive in very high pressure lubricants. In fluorescent and highintensity discharge ballasts manufactured prior to 1979 (U.S. EPA, 1998).
PCB-1248 and PCB-1254 were used instead of silicone oils in vacuum pumps (Monsanto, 1960).
At a concentration of 5 to 25 wt %, increased the effective kill-life of the lindane spray up to 10 times. May have been used in chlordane and BHC insecticide formulations (Monsanto, 1960).
[Definition]

ChEBI: 3,3',5,5'-tetrachlorobiphenyl is a tetrachlorobiphenyl that is biphenyl in which both phenyl groups are substituted by chlorines at positions 3 and 5. It is a tetrachlorobiphenyl and a dichlorobenzene.
[Environmental Fate]

Biological. Reported degradation products by the microorganism Alcaligenes BM-2 for a mixture of polychlorinated biphenyls include monohydroxychlorobiphenyl, 2-hydroxy-6- oxochlorophenylhexa-2,4-dieonic acid, chlorobenzoic acid, chlorobenzoylpropionic acid, chlorophenylacetic acid, and 3-chlorophenyl-2-chloropropenic acid (Yagi and Sudo, 1980). When PCB-1248 (5 and 10 mg/) was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, no biodegradation was observed (Tabak et al., 1981).
Chemical/Physical. Heating PCB-1248 in oxygen at 270–300 °C for 1 wk resulted in the formation of mono-, di-, tri-, tetra-, and pentachlorodibenzofurans (PCDFs). At temperatures greater than 330 °C, PCDFs decompose (Morita et al., 1978).
PCB-1248 will not hydrolyze to any reasonable extent (Kollig, 1993).
When PCB-1248 was heated up to 315 °C in a closed system, no appreciable decomposition was observed (Monsanto, 1960).
Mackay and Wolkoff (1973) estimated an evaporation half-life of 58.3 min from a surface water body that is 25 °C and 1 m deep.
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