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ChemicalBook--->CAS DataBase List--->1260119-00-3

1260119-00-3

1260119-00-3 Structure

1260119-00-3 Structure
IdentificationBack Directory
[Name]

Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0)
[CAS]

1260119-00-3
[Synonyms]

NH2-UiO-66
UIO-66-NH2
NH2-UIO-66(Zr)
UiO-66-NH2(Zr)
MOF:UiO-66(Zr)-NH2
Zirconium aminobenzenedicarboxylate MOF
ZIRCONIUMAMINOBENZENEDICARBOXYLATEMOF(UIO-66-BDC-NH2,BDC-NH2:ZR=0.9-1.0)
UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0,Zirconium aminobenzenedicarboxylate MOF
[Molecular Formula]

C48H30N6O32Zr6
[MOL File]

1260119-00-3.mol
[Molecular Weight]

1750.12
Chemical PropertiesBack Directory
[form ]

solid
[color ]

Yellow
[InChI]

InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12
[InChIKey]

SGCQKKMGUIJGFK-UHFFFAOYSA-B
Questions And AnswerBack Directory
[Uses]

Zirconium aminobenzenedicarboxylate MOF (UiO-66-BDC-NH2, BDC-NH2:Zr=0.9-1.0) Useful MOF for adsorption of CO2 applications
Catalyst MOF used in the conversion of toxic agents to non-toxic products
Hazard InformationBack Directory
[Definition]

UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].
[References]

[1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197.
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