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ChemicalBook--->CAS DataBase List--->126-80-7

126-80-7

126-80-7 Structure

126-80-7 Structure
IdentificationBack Directory
[Name]

1,3-BIS(3-GLYCIDOXYPROPYL)TETRAMETHYLDISILOXANE
[CAS]

126-80-7
[Synonyms]

NSC 93976
1,3-BIS-(3-GLYCIDYLOXYPROPYL)-TETRA-
BIS(3-GLYCIDOXYPROPYL)TETRAMETHYLDISILOXANE
1,3-BIS(GLYCIDOXYPROPYL)TETRAMETHYLDISILOXANE
1,3-BIS(3-GLYCIDOXYPROPYL)TETRAMETHYLDISILOXANE
Bis-(3-glycidyloxypropyl)-tetramethyldisiloxane
1,3-Bis(3-glycidoxypropyl)-1,1,3,3-tetraMethyldi
1 3-BIS(3-GLYCIDYLOXYPROPYL)TETRA-METHYLDISILOXANE
1,3-bis[3-(2,3-epoxypropoxy)propyl]tetramethylsiloxane
1,3-Di(3-glycidoxypropyl)-1,1,3,3-tetramethyldisiloxane
1,3-BIS(3-(2,3-EPOXYPROPOXY)PROPYL)TETRAMETHYLDISILOXANE
1,3-Bis(3-glycidoxy propyl)-1,1,3,3-tetraMethyldisiloxane
1,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-disiloxan
1,1,3,3-tetramethyl-1,3-bis[3-(oxiranylmethoxy)propyl]-Disiloxane
1,1,3,3-tetramethyl-1,3-bis-(3-oxiranylmethoxy-propyl)-disiloxane
1,3-bis(3-(2,3-epoxypropoxy)propyl)-1,1,3,3-tetramethyldisiloxane
Polydimethylsiloxane, epoxypropoxypropyl terminated, viscosity 1-2 cSt.
[dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silyl]oxy-dimethyl-[3-(oxiran-2-ylmethoxy)propyl]silane
[EINECS(EC#)]

204-803-9
[Molecular Formula]

C16H34O5Si2
[MDL Number]

MFCD00039672
[MOL File]

126-80-7.mol
[Molecular Weight]

362.61
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

184 °C2 mm Hg(lit.)
[density ]

0.996 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.452
[Fp ]

110°C
[Specific Gravity]

0.996
[Hydrolytic Sensitivity]

3: reacts with aqueous base
[BRN ]

223966
[InChI]

InChI=1S/C16H34O5Si2/c1-22(2,9-5-7-17-11-15-13-19-15)21-23(3,4)10-6-8-18-12-16-14-20-16/h15-16H,5-14H2,1-4H3
[InChIKey]

MFIBZDZRPYQXOM-UHFFFAOYSA-N
[SMILES]

[Si](C)(C)(CCCOCC1CO1)O[Si](C)(C)CCCOCC1CO1
[EPA Substance Registry System]

1,1,3,3-Tetramethyl-1,3-bis[3-glycidyloxypropyl]disiloxane (126-80-7)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

Yes
Hazard InformationBack Directory
[Uses]

1,3-Bis(3-glycidyloxypropyl)tetramethyldisiloxane can be used:
  • As a starting material to synthesize functional poly(siloxane amine)s via an amine-epoxy click polymerization for material and biological applications.
  • To prepare polymer electrolyte membranes (PEM) for fuel cell applications.

[Synthesis]

1,1,3,3-Tetramethyldisiloxane and 1.1 equiv of allyl glycidyl ether (calculated to each Si-H group) were placed into the reaction vessel and heated up to 90 °C. Then the appropriate amount of [{Rh(OSiMe3)cod}2] (in the ratio 10-5 mol per mol Si-H) was added as a catalyst, and the reaction was continued for the next 2 h to give a crude product 1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane.
1,3-bis(3-glycidoxypropyl)tetramethyldisiloxane
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