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ChemicalBook--->CAS DataBase List--->1239478-87-5

1239478-87-5

1239478-87-5 Structure

1239478-87-5 Structure
IdentificationBack Directory
[Name]

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
[CAS]

1239478-87-5
[Synonyms]

Ad-BGPhos
AdBippyphos
Adamantyl-BippyPhos
5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole
5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole
1,4'-Bi-1H-pyrazole, 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-1',3',5'-triphenyl-
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole[Adamantyl-BippyPhos
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, (Adamantyl-BippyPhos)
5-[Di(1-adaMantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97+% (AdaMantyl-BippyPhos)
[Molecular Formula]

C44H47N4P
[MDL Number]

MFCD22200502
[MOL File]

1239478-87-5.mol
[Molecular Weight]

662.84
Chemical PropertiesBack Directory
[Melting point ]

295-300°C
[storage temp. ]

2-8°C
[form ]

solid
[pka]

-0.58±0.19(Predicted)
[color ]

white to light yellow
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37
[WGK Germany ]

3
[TSCA ]

No
Hazard InformationBack Directory
[Uses]

5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole can be used as a catalyst.
[Uses]

5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole (Ad-BippyPhos) is an effective ligand that catalyzes C-O coupling reactions of aryl and heteroaryl bromides/chlorides with primary aliphatic alcohols. It can also be used as a catalyst in the synthesis of fluorinated anilines by coupling fluoroalkylamines with aryl bromides and chlorides.
[reaction suitability]

reagent type: ligand
Spectrum DetailBack Directory
[Spectrum Detail]

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole(1239478-87-5)1HNMR
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole(1239478-87-5)31PNMR
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