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ChemicalBook--->CAS DataBase List--->12108-04-2

12108-04-2

12108-04-2 Structure

12108-04-2 Structure
IdentificationBack Directory
[Name]

CYCLOPENTADIENYLVANADIUM TETRACARBONYL
[CAS]

12108-04-2
[Synonyms]

TETRACARBONYLCYCLOPENTADIENYLVANADIUM
carbon monoxide,cyclopentane,vanadium
CYCLOPENTADIENYLVANADIUM TETRACARBONYL
Vanadium cyclopentadienyltetracarbonyl
Tetracarbonyl-pi-cyclopentadienylvanadium
Tetracarbonylcyclopentadienylvanadium, 97+%
Vanadium, tetracarbonyl-pi-cyclopentadienyl-
Cyclopentadienylvanadium tetracarbonyl, 97+%
Cyclopentadienylvanadiumtetracarbonyl,min.97%
Cyclopentadienylvanadium tetracarbonyl, min. 97%
tetracarbonyl(eta5-cyclopenta-2,4-dien-1-yl)vanadium
Vanadium, tetracarbonyl(eta5-2,4-cyclopentadien-1-yl)-
[EINECS(EC#)]

235-163-9
[Molecular Formula]

C9H5O4V 5*
[MDL Number]

MFCD00014259
[MOL File]

12108-04-2.mol
[Molecular Weight]

228.08
Chemical PropertiesBack Directory
[Melting point ]

138°C
[Boiling point ]

80-110°C 0,1mm
[Fp ]

80-100°C/0.1mm subl.
[solubility ]

sol benzene, 1,2-dichloroethane, THF; slightly sol hexane.
[form ]

crystal
[color ]

orange to red
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Air Sensitive
[Exposure limits]

NIOSH: Ceiling 0.05 mg/m3
Safety DataBack Directory
[Risk Statements ]

23/24/25
[Safety Statements ]

26-28-36/37/39-45
[RIDADR ]

3285
[HazardClass ]

6.1
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Employed as pharmaceutical intermediates.
[Uses]

Tetracarbonylcyclopentadienylvanadium is used as a catalyst for stereoselective alkene oxidation; forms an anionic hydride complex which reduces dibromides; reacts with alkynes to form cyclic ketones.
[storage]

CYCLOPENTADIENYLVANADIUM TETRACARBONYL is stored and handled in an inert atmosphere.
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1314-62-1

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