Identification | Back Directory | [Name]
CYCLOPENTADIENYLVANADIUM TETRACARBONYL | [CAS]
12108-04-2 | [Synonyms]
TETRACARBONYLCYCLOPENTADIENYLVANADIUM carbon monoxide,cyclopentane,vanadium CYCLOPENTADIENYLVANADIUM TETRACARBONYL Vanadium cyclopentadienyltetracarbonyl Tetracarbonyl-pi-cyclopentadienylvanadium Tetracarbonylcyclopentadienylvanadium, 97+% Vanadium, tetracarbonyl-pi-cyclopentadienyl- Cyclopentadienylvanadium tetracarbonyl, 97+% Cyclopentadienylvanadiumtetracarbonyl,min.97% Cyclopentadienylvanadium tetracarbonyl, min. 97% tetracarbonyl(eta5-cyclopenta-2,4-dien-1-yl)vanadium Vanadium, tetracarbonyl(eta5-2,4-cyclopentadien-1-yl)- | [EINECS(EC#)]
235-163-9 | [Molecular Formula]
C9H5O4V 5* | [MDL Number]
MFCD00014259 | [MOL File]
12108-04-2.mol | [Molecular Weight]
228.08 |
Chemical Properties | Back Directory | [Melting point ]
138°C | [Boiling point ]
80-110°C 0,1mm | [Fp ]
80-100°C/0.1mm subl. | [solubility ]
sol benzene, 1,2-dichloroethane, THF; slightly sol hexane. | [form ]
crystal | [color ]
orange to red | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Air Sensitive | [Exposure limits]
NIOSH: Ceiling 0.05 mg/m3 |
Hazard Information | Back Directory | [Uses]
Employed as pharmaceutical intermediates. | [Uses]
Tetracarbonylcyclopentadienylvanadium is used as a catalyst for stereoselective alkene oxidation; forms an anionic hydride complex which reduces dibromides; reacts with alkynes
to form cyclic ketones. | [storage]
CYCLOPENTADIENYLVANADIUM TETRACARBONYL is stored and handled in an inert atmosphere. |
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