| Identification | More | [Name]
4-VINYLCYCLOHEXENE DIOXIDE | [CAS]
106-87-6 | [Synonyms]
1-EPOXYETHYL-3.4-EPOXYCYCLOHEXANE
3-EPOXYETHYL-7-OXABICYCLO [4.1.0] HEPTANE
4-VINYL-1-CYCLOHEXENE DIEPOXIDE
4-VINYL-1-CYCLOHEXENE DIOXIDE
4-VINYLCYCLOHEXENE DIOXIDE
ERL 4206
ERL(R) 4206
VCD
VCHD
VINYL-4-CYCLOHEXENE DIOXIDE
VINYLCYCLOHEXENE DIOXIDE
1,0]heptane,3-oxiranyl-7-Oxabicyclo[4
1,2-epoxy-4-(epoxyethyl)cyclohexane
1-ethyleneoxy-3,4-epoxycyclohexane
1-vinyl-3-cyclohexenedioxide
3-(1,2-epoxyethyl)-7-oxabicyclo(4.1.0)heptane
3-(epoxyethyl)-7-oxabicyclo(4.1.0)heptan
3-epoxyethyl-7-oxabicycloheptane
3-oxiranyl-7-oxabicyclo(4.1.0)heptan
3-oxiranyl-7-oxabicyclo(4.1.0)heptane | [EINECS(EC#)]
203-437-7 | [Molecular Formula]
C8H12O2 | [MDL Number]
MFCD00022354 | [Molecular Weight]
140.18 | [MOL File]
106-87-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Vinyl cyclohexene dioxide is a colorless liquid | [Melting point ]
-55°C | [Boiling point ]
230-232 °C(lit.) | [density ]
1.094 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.477(lit.)
| [Fp ]
225 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Colorless or pale yellow
liquid | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents, alcohols, amines and other compounds containg an active hydrogen. Hydrolyzes slowly in water. | [Water Solubility ]
154.7g/L(20 ºC) | [BRN ]
106071 | [CAS DataBase Reference]
106-87-6(CAS DataBase Reference) | [IARC]
2B (Vol. Sup 7, 60) 1994 | [EPA Substance Registry System]
106-87-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R68/20/21/22:Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed .
R68:Possible risk of irreversible effects. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24:Avoid contact with skin .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
1
| [RTECS ]
RN8640000
| [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Safety Profile]
Confirmed carcinogen
with experimental carcinogenic and
tumorigenic data. Poison by unspecified
route. Moderately toxic by ingestion and
skin contact. Mildly toxic by inhalation.
Experimental reproductive effects. Mutation
data reported. A severe skin irritant.Combustible when exposed to heat or
flame. To fight fire, use water, foam, dry
chemical. When heated to decomposition it
emits acrid smoke and irritating fumes. | [Hazardous Substances Data]
106-87-6(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Clear colorless liquid. Sets to glass at-67°F. Faint olefinic odor. | [Reactivity Profile]
1-VINYL-3-CYCLOHEXENE DIOXIDE(106-87-6) reacts with active hydrogen compounds (such as alcohols and amines). . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts. | [Air & Water Reactions]
Water soluble. Hydrolyzes slowly in water. | [Potential Exposure]
This material is used as a monomer in
the production of epoxy resins for coatings and adhesives;
as a chemical intermediate and as a reactive diluent. | [Fire Hazard]
This chemical is combustible. | [First aid]
Eye Contact: Immediately remove any contact
lenses and flush with large amounts of water for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately.
Skin Contact: Quickly remove contaminated clothing.
Immediately wash contaminated skin with large amounts of
water. Seek medical attention.
Breathing: Remove the person from exposure. Begin (using
universal precautions, including resuscitation mask) if
breathing has stopped and CPR if heart action has stopped.
Transfer promptly to a medical facility.
Ingestion: If convulsions are not present, give a glass or
two of water or milk to dilute the substance. Assure that
the person’s airway is unobstructed and contact a hospital
or poison center immediately for advice on whether or not
to induce vomiting. | [Shipping]
UN2810 Toxic liquids, organic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required. | [Incompatibilities]
When heated or in contact with catalysts,
epoxides may cause violent polymerization. Epoxides are
incompatible with reducing agents and oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. May react, possibly violently,
with water in the presence of acid and other catalysts.
Reacts with alcohols, amines and other active
hydrogen compounds. Slowly hydrolyzes in water. | [Chemical Properties]
colourless liquid. Combustible.
| [Chemical Properties]
Vinyl cyclohexene dioxide is a colorless liquid | [Waste Disposal]
Concentrated waste containing
no peroxides: discharge liquid at a controlled rate near
a pilot flame. Concentrated waste containing peroxides:
perforation of a container of the waste from a safe distance
followed by open burning. | [Uses]
Vinylcyclohexene dioxide (VCD) may be used to study and understand its effect on ovarian follicles and effects on epithelial differentiation. | [Uses]
As a chemical intermediate and as a
reactive diluent for diepoxides and epoxy
resins. | [Uses]
Vinylcyclohexene dioxide (VCD) is used to study toxicity as an ovotoxin,and it's also used to understand its mechanisms of toxicity towards ovarian follicles and effects on epithelial differentiation. | [Definition]
ChEBI: The diepoxide of 4-vinylcyclohexene. | [Production Methods]
VCHD is manufactured by epoxidation of 4-vinylcyclohexene
with peroxyacetic acid . | [Hazard]
Toxic by ingestion and skin absorption,
strong irritant to skin and tissue. Female and male
reproductive damage. Possible carcinogen. | [Health Hazard]
Vinyl cyclohexene dioxide
(VCD) is an irritant to the skin, eyes, and respiratory
system. It is ovotoxic and carcinogenic
in experimental animals. | [Carcinogenicity]
4-Vinyl-1-cyclohexene diepoxide is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity fromstudies in experimental animals. |
|
|