Identification | Back Directory | [Name]
SHVO'S CATALYST | [CAS]
104439-77-2 | [Synonyms]
Shvo Catalyst SHVO'S CATALYST 1-HYDROXYTETRAPHENYL-CYCLOPENTADIENYL(TE 1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-HYDROTETRACARBONYLDIRUTHENIUM (II) 1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-1-HYDROTETRACARBONYLDIRUTHENIUM(II) 1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-u-hydrotetracarbonyldiruthenium(II) 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II) 1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II) 1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-Mu-hydrotetracarbonyldirutheniuM(II) 1-HYDROXYTETRAPHENYL-CYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)-MU-HYDROTETRACARBONYLDIRUTHENIUM(II) 1-HYDROXYTETRAPHENYLCYCLOPENTADIENYL(TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE)--HYDROTETRACARBONYLDIRUTHENIUM (II) 98% 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-^M-hydrotetracarbonyldirutheniuM(II), 98% 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldirutheniuM(II) SHVO'S CATALYST 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-mu-hydrotetracarbonyldiruthenium(II),98%SHVO'SCATALYST 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II), 98% SHVO'S CATALYST TETRACARBONYL-MU-HYDRO[(1,2,3,4,5-H)-1-HYDROXYLATO-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL][(1,2,3,4,5-H)-1-HYDROXY-2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-YL]DIRUTHENIUM Ruthenium,tetracarbonyl-m-hydro[(1,2,3,4,5-h)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]di- Shvos Catalyst, Tetracarbonyl-μ-hydro[(1,2,3,4,5-H)-1-hydroxylato-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-H)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]diruthenium | [Molecular Formula]
C62H41O6Ru2 5* | [MDL Number]
MFCD03840556 | [MOL File]
104439-77-2.mol | [Molecular Weight]
1084.13 |
Chemical Properties | Back Directory | [Melting point ]
223-227 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
DMSO (Slightly) | [form ]
Powder | [color ]
orange | [Water Solubility ]
Soluble in water and polar organic solvents. | [Sensitive ]
Moisture Sensitive | [Merck ]
14,8483 | [CAS DataBase Reference]
104439-77-2 |
Hazard Information | Back Directory | [Uses]
Catalyst in organic syntheses for hydrogen transfers including disproportionation of aldehydes, reduction of ketones and aldehydes, oxidation and/or racemization of alcohols and amines. |
Questions And Answer | Back Directory | [Reactions]
- In conjugation with lipase, ruthenium catalyst used in the asymmetric transformation of ketones and enol acetates into chiral acetates.
- Dynamic kinetic resolution resulting from the ruthenium catalyzed racemization of enzymatically- resolved substrates.
- Conversion of secondary amines to primary amines in the presence of ammonia.
- Co-catalyt for aerobic lactonization of diols.
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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