Identification | Back Directory | [Name]
N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine | [CAS]
1010396-31-2 | [Synonyms]
VNPB N,N'-Bis(naphthalen-1-yl)-N,N'-bis(4-vinyl-phenyl)benzidine N4,N4′-di(Naphthalen-1-yl)-N4,N4′-bis(4- vinylphenyl)biphenyl-4,4′-diamine N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine [1,1'-Biphenyl]-4,4'-diamine, N4,N4'-bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl- N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine ISO 9001:2015 REACH | [Molecular Formula]
C48H36N2 | [MDL Number]
MFCD27978272 | [MOL File]
1010396-31-2.mol | [Molecular Weight]
640.81 |
Chemical Properties | Back Directory | [Boiling point ]
825.3±65.0 °C(Predicted) | [density ]
1.192±0.06 g/cm3(Predicted) | [solubility ]
THF: soluble chloroform: soluble toluene: soluble | [pka]
0.06±0.50(Predicted) | [λmax]
350 nm±5 nm in THF (UV) | [InChIKey]
WTEWXIOJLNVYBZ-UHFFFAOYSA-N | [SMILES]
C1(C2=CC=C(N(C3=CC=C(C=C)C=C3)C3=C4C(C=CC=C4)=CC=C3)C=C2)=CC=C(N(C2=CC=C(C=C)C=C2)C2=C3C(C=CC=C3)=CC=C2)C=C1 |
Hazard Information | Back Directory | [Uses]
N4,N4μ-Di(naphthalen-1-yl)-N4,N4μ-bis(4-vinylphenyl)biphenyl-4,4μ-diamine, also known as VNPB, is a solution-processable Hole Transport / Electron Blocking Layer (HTL / EBL) material popularly used in organic electronics, such as OLEDs and perovskite solar cells . In OLED devices, the use of VNPB enabled the maximum current efficiency of 22.2 Cd/A, compared to 9.7 Cd/A in the reference device without VNPB, and the device lifetime was extended by up to 74.8% . VNPB allowed a simple and additive-free strategy to prevent the formation of defects in solution processed thin-film stacks made of small-molecular materials. In solar cells, VNPB increased open-circuit voltage (VOC) and power conversion efficiency (PCE) of wide-bandgap perovskite solar cells by changing the hole transport layer (HTL) from commonly used poly(bis(4-phenyl)(2,4,6-trimethylphenyl)amine) (PTAA) to in-situ cross-linked small mol. VNPB . PCEs of 24.9% and 25.4% have been achieved in perovskite/perovskite and perovskite/silicon tandem solar cells, resp. |
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Shanghai Uchem Inc.
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Henan Alfachem Co.,Ltd.
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3A Chemicals
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