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ChemicalBook--->CAS DataBase List--->1010396-31-2

1010396-31-2

1010396-31-2 Structure

1010396-31-2 Structure
IdentificationBack Directory
[Name]

N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine
[CAS]

1010396-31-2
[Synonyms]

VNPB
N,N'-Bis(naphthalen-1-yl)-N,N'-bis(4-vinyl-phenyl)benzidine
N4,N4′-di(Naphthalen-1-yl)-N4,N4′-bis(4- vinylphenyl)biphenyl-4,4′-diamine
N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine
[1,1'-Biphenyl]-4,4'-diamine, N4,N4'-bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-
N4,N4'-Bis(4-ethenylphenyl)-N4,N4'-di-1-naphthalenyl-[1,1'-biphenyl]-4,4'-diamine ISO 9001:2015 REACH
[Molecular Formula]

C48H36N2
[MDL Number]

MFCD27978272
[MOL File]

1010396-31-2.mol
[Molecular Weight]

640.81
Chemical PropertiesBack Directory
[Boiling point ]

825.3±65.0 °C(Predicted)
[density ]

1.192±0.06 g/cm3(Predicted)
[solubility ]

THF: soluble
chloroform: soluble
toluene: soluble
[pka]

0.06±0.50(Predicted)
[λmax]

350 nm±5 nm in THF (UV)
[InChIKey]

WTEWXIOJLNVYBZ-UHFFFAOYSA-N
[SMILES]

C1(C2=CC=C(N(C3=CC=C(C=C)C=C3)C3=C4C(C=CC=C4)=CC=C3)C=C2)=CC=C(N(C2=CC=C(C=C)C=C2)C2=C3C(C=CC=C3)=CC=C2)C=C1
Hazard InformationBack Directory
[Uses]

N4,N4μ-Di(naphthalen-1-yl)-N4,N4μ-bis(4-vinylphenyl)biphenyl-4,4μ-diamine, also known as VNPB, is a solution-processable Hole Transport / Electron Blocking Layer (HTL / EBL) material popularly used in organic electronics, such as OLEDs and perovskite solar cells .
In OLED devices, the use of VNPB enabled the maximum current efficiency of 22.2 Cd/A, compared to 9.7 Cd/A in the reference device without VNPB, and the device lifetime was extended by up to 74.8% . VNPB allowed a simple and additive-free strategy to prevent the formation of defects in solution processed thin-film stacks made of small-molecular materials.
In solar cells, VNPB increased open-circuit voltage (VOC) and power conversion efficiency (PCE) of wide-bandgap perovskite solar cells by changing the hole transport layer (HTL) from commonly used poly(bis(4-phenyl)(2,4,6-trimethylphenyl)amine) (PTAA) to in-situ cross-linked small mol. VNPB . PCEs of 24.9% and 25.4% have been achieved in perovskite/perovskite and perovskite/silicon tandem solar cells, resp.
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